Chemistry I / Entropy and the Second Law
Practice question · Numerical answer

A system has 4 accessible microstates. Using S=klnWS = k \ln W with k=1.381×1023k = 1.381 \times 10^{-23} J/K, compute its entropy in units of 102310^{-23} J/K, to two decimal places.

Hints
  1. Take the natural logarithm of the number of microstates, then multiply by k.
  2. ln 4 = 1.386, so compute 1.381 x 1.386.
Show the answer

1.91 (answers within ±0.04 count)

Why

S=klnW=1.381×1023×ln4=1.381×1.386=1.91×1023S = k\ln W = 1.381 \times 10^{-23} \times \ln 4 = 1.381 \times 1.386 = 1.91 \times 10^{-23} J/K. Entropy grows only logarithmically, so doubling the microstate count adds a fixed amount rather than doubling SS.

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