Chemistry I / Hybridisation and Molecular Orbitals
Practice question · Match the pairs

Match each model or feature to what it accounts for.

  • Bonding molecular orbital
  • Antibonding molecular orbital
  • sp3sp^3 hybridisation
  • Unhybridised p orbital
  • Supplies the second component of a double bond
  • Four equivalent bonds at 109.5 degrees
  • A node between the nuclei that weakens binding
  • Electron density concentrated between the nuclei
Hints
  1. Separate what builds the bond from what cancels it.
  2. The orbital left over from hybridisation is what makes multiple bonds possible.
Show the answer
  • Bonding molecular orbital Electron density concentrated between the nuclei
  • Antibonding molecular orbital A node between the nuclei that weakens binding
  • sp3sp^3 hybridisation Four equivalent bonds at 109.5 degrees
  • Unhybridised p orbital Supplies the second component of a double bond
Why

Bonding MOs pile electron density between the nuclei; antibonding MOs put a node there; sp3sp^3 explains tetrahedral geometry; and the leftover unhybridised pp orbital supplies pi overlap.

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