Chemistry I / Periodic Properties
Practice question · Numerical answer

For a valence electron of silicon (Z=14Z = 14), the shielding constant is S=9.85S = 9.85 by Slater’s rules. Compute the effective nuclear charge, to two decimal places.

Hints
  1. Effective nuclear charge is the actual charge minus what is screened.
  2. Compute 14 - 9.85.
Show the answer

4.15 (answers within ±0.03 count)

Why

Zeff=ZS=149.85=4.15Z_{\text{eff}} = Z - S = 14 - 9.85 = 4.15. The valence electron feels roughly a +4+4 pull rather than the full +14+14, which is why silicon is far larger than its nuclear charge alone would suggest.

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