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Chemistry

Stoichiometric relationships

Physics I 178 words Free to read

Stoichiometry is the quantitative backbone of chemistry — it links the amounts of reactants consumed to products formed via mole ratios.

Balanced equation

aA+bB    cC+dDa\,A + b\,B \;\longrightarrow\; c\,C + d\,D

The coefficients a,b,c,da, b, c, d are the stoichiometric coefficients. Mass and charge must be conserved.

Conversion chain

grams  ÷M  moles  ×ratio  moles of target  ×M  grams\text{grams} \;\xrightarrow{\div\,M}\; \text{moles} \;\xrightarrow{\times\,\text{ratio}}\; \text{moles of target} \;\xrightarrow{\times\,M}\; \text{grams}

Limiting reagent — The reactant that runs out first determines the maximum yield. To find it, convert all reactants to moles and compare to the required ratio.

Concentration measures

MeasureFormula
Molarity MMnsoluteVsolution\dfrac{n_{\text{solute}}}{V_{\text{solution}}}
Mole fraction xix_ininj\dfrac{n_i}{\sum n_j}
Molality mmnsolutemsolvent (kg)\dfrac{n_{\text{solute}}}{m_{\text{solvent (kg)}}}

Percent yield

%  yield=actual yieldtheoretical yield×100\%\;\text{yield} = \frac{\text{actual yield}}{\text{theoretical yield}}\times 100

Tip: Dimensional analysis is your best friend. Track units through every step and cancel them — if the units come out wrong, the calculation is wrong.
Common pitfall: Balanced coefficients relate moles, never grams. Converting masses to moles before using the ratio — and back after — is the non-negotiable detour of every stoichiometry problem.
Chemistry: Stoichiometric relationships

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