Chemistry I / Atomic Spectra and the Quantum Atom
Practice question · Sort into groups

Sort each observation by whether the classical wave picture can account for it.

Groups: Explained by waves alone · Requires photons

Hints
  1. Ask whether the effect depends on energy arriving in indivisible packets.
  2. Anything involving a sharp energy threshold or discrete levels needs photons.
Show the answer

Explained by waves alone: A beam bending as it passes into glass, Interference fringes from a double slit

Requires photons: A sharp threshold frequency for electron ejection, A glowing gas showing only a few discrete wavelengths, A photocurrent that stops dead below a cut-off colour

Why

Refraction and interference are pure wave behaviour and never needed quantisation. A frequency threshold, discrete spectral lines and instant ejection at low intensity all require energy to arrive in indivisible packets of hνh\nu.

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