Chemistry I / Buffers, Hydrolysis and Titration
Practice question · Numerical answer

A buffer contains equal concentrations of a weak acid and its conjugate base. The acid has pKa=4.75\mathrm{p}K_a = 4.75. Compute the pH of the buffer.

Hints
  1. Use the Henderson-Hasselbalch equation.
  2. When the two concentrations are equal, the logarithm of their ratio is zero.
Show the answer

4.75 (answers within ±0.05 count)

Why

With [A]=[HA][\mathrm{A^-}] = [\mathrm{HA}] the ratio is 1 and log1=0\log 1 = 0, so pH=pKa=4.75\mathrm{pH} = \mathrm{p}K_a = 4.75. This is why a buffer is chosen by matching its pKa\mathrm{p}K_a to the pH you want to hold.

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