Chemistry I / Buffers, Hydrolysis and Titration
Practice question · Match the pairs

Match each titration pairing to the pH at its equivalence point.

  • Strong acid with strong base
  • Weak acid with strong base
  • Strong acid with weak base
  • Half-equivalence of a weak acid
  • Equal to the acid pKa
  • Below 7
  • Exactly 7
  • Above 7
Hints
  1. Ask which ion is left in solution once the reaction is complete.
  2. A leftover conjugate base raises the pH; a leftover conjugate acid lowers it.
Show the answer
  • Strong acid with strong base Exactly 7
  • Weak acid with strong base Above 7
  • Strong acid with weak base Below 7
  • Half-equivalence of a weak acid Equal to the acid pKa
Why

Only strong-with-strong leaves ions that do not hydrolyse, giving a neutral 7. A weak parent on either side leaves a hydrolysing conjugate that pushes the equivalence pH away from neutral.

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