Chemistry I / Gibbs Free Energy and Spontaneity
Practice question · Multiple choice

Diamond converts to graphite with ΔG<0\Delta G < 0 at room temperature, yet diamonds do not visibly change. What does this show?

Hints
  1. Separate what thermodynamics predicts from what kinetics controls.
  2. A large activation barrier can make a spontaneous reaction immeasurably slow.
Show the answer

A. Spontaneity says nothing about rate

Why

Thermodynamics says the conversion can happen; kinetics says how fast. An enormous activation barrier keeps the rate effectively zero, so a genuinely spontaneous process takes geological time. A barrier affects rate, not ΔG\Delta G.

Read the lesson: Gibbs Free Energy and Spontaneity →

Practise Gibbs Free Energy and Spontaneity

The app has 4 more questions on this lesson, and keeps your place in the course. Chemistry I is free to start.

More questions on Gibbs Free Energy and Spontaneity